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New catalysts enable photocatalytic version of water gas shift reaction for H2 production

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Politécnica de Valencia (Spain) have found that noble metal nanoparticles supported on titanium dioxide or cerium dioxide can catalyze the industrially important water gas shift (WGS) reaction for hydrogen production at ambient temperatures using visible light irradiation. —Sastre et al. Energy Environ. doi: 10.1039/C3EE40656C.

Water 186
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Researchers at UC Santa Barbara develop efficient and stable plasmonic water splitter; potential alternative to semiconductor-based solar conversion

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Researchers at UC Santa Barbara have developed an efficient, autonomous solar water-splitting device based on a gold nanorod array in which essentially all charge carriers involved in the oxidation and reduction steps arise from the hot electrons resulting from the excitation of surface plasmons in the nanostructured gold (plasmonic water-splitter).

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Power-to-Gas project awarded DECC grant funding

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Up to £40,000 (US$62,160) was made available to cover parts of the costs of developing a detailed feasibility study for a 1MW power-to-gas facility to be built in the UK starting in the second half of 2013. Using Electrochaea ’s biological catalyst, the hydrogen is then combined with CO 2 (e.g.

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HELMETH project targeting >85% efficiencies for power-to-gas; high-temperature electrolysis

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The HELMETH (“Integrated High-temperature ELectrolysis and METHanation for Effective Power to Gas Conversion”) project, coordinated by Karlsruhe Institue of Technology (KIT) is targeting power-to-gas (PtG) system efficiencies of more than 85% through better synergies with existing process steps. Power-to-gas (e.g.,

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New version of Argonne lifecycle model for water footprint of biofuels now includes cellulosic feedstocks

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of the online tool Water Assessment for Transportation Energy Resources ( WATER ) this week. This latest version of WATER allows, for the first time, biofuels manufacturers to analyze water consumption associated with use of cellulosic feedstocks such as residue left from lumber production and other wood-based resources.

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USDA provides $91M loan guarantee to Cool Planet for biogasoline blendstock plant; biomass pyrolysis and catalytic conversion

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Gas chromatography comparison of Conoco fuel and a Conoco-CoolPlanet blend. Cool Planet has devised a biomass-to-liquids thermochemical conversion process that simultaneously produces liquid fuels and sequesterable biochar useful as a soil amendment. One of the catalytic conversion processes creates the high-octane gasoline blendstock.

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New inexpensive catalyst for conversion of CO2 to CO could help with storage of renewable energy

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CO can then be reacted with H 2 O via the water?gas gas shift to generate H 2 , and this CO/H 2 mixture (syngas) can be used to generate synthetic petroleum and liquid fuels using Fischer?Tropsch DiMeglio and Joel Rosenthal (2013) Selective Conversion of CO2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst.