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Lithiumsulfur batteries are of great interest due to their high specific energy and relatively low cost (e.g., A team at Stanford University lef by Profesor Yi Cui has now identified a new capacity fading mechanism of the sulfur cathodes and developed a new approach to overcoming this mechanism. Credit: ACS, Zheng et al.
Researchers at Chalmers University of Technology, Sweden, have developed a free-standing reduced graphene oxide (r-GO) aerogel for use as a supporting electrode for the electrochemical redox reaction of sulfur in a catholyte-based lithium-sulfur battery. An illustration of the Chalmers design for a lithiumsulfur battery.
million), 43-month LithiumSulfur for Safe Road Electrification (LISA) project will launch 1 January 2019 in Europe. The overall goal is to design and manufacture a lithium-sulfur technology that will enable safe electrification of EV applications. million (US$8.9-million),
Kentucky Governor Steve Beshear announced that start-up lithium-sulfur battery company NOHMs (Nano Organic Hybrid Materials) Technologies Inc. has selected to locate its research, manufacturing and product development facility for military, cell phone and electric vehicle lithium-ion batteries in Lexington.
Anion-redox lithium–sulfur (Li–S) is one of the most promising conversion battery chemistries with high theoretical cathode energy density of 2,600 Wh kg -1 based on the weight of Li 2 S, S 8 + 16 e? Typical sulfur cathodes are made up of 20 to 30 percent carbon, he says, but the new version needs only 10 percent carbon.
Researchers at the University of Texas at Austin, led by Prof. enables the direct use of commercially available bulk Li 2 S particles as high-capacity cathode materials for rechargeable Li?S The ability to use commercially available bulk particles could significantly decrease the manufacturing cost of Li?S S batteries.
A team from Lawrence Berkeley National Laboratory and Tsinghua University (China) have synthesized graphene oxide-sulfur (GO-S) nanocomposite cathodes and applied them in lithium/sulfur cells to show a high reversible capacity of 950-1400 mAh g -1 and stable cycling for more than 50 deep cycles at 0.1C (1C = 1675 mA g -1 ).
Researchers at Shanghai Jiao Tong University have developed a gel-like electrolyte induced by fumed alumina for dendrite-free Li deposition, lower over-potential and better cycle stability in lithium-sulfur batteries. Hence, it is necessary to address these issues prior to its large-scale commercialization. …
Australia-based Li-S Energy has entered into an agreement with Janus Electric to develop and to test lithiumsulfur and/or lithium-metal battery cells to suit the requirements of the Janus Electric exchangeable prime mover battery packs. MWh) by the end of 2023, with additional demand growth expected in future years.
The University of Michigan (U-M) and Shanghai Jiao Tong University (SJTU) have selected six research teams to share $1.05 The renewable energy projects are: Safe, high-performance lithium-sulfur batteries for electric vehicle applications. and Chinese governments, as well as from industry.
One of the main limiters to the commercialization of high energy density lithium-sulfur batteries is the dissolution of long-chain lithium polysulfides into the electrolyte, which limits cycling performance. —Oh et al. and Yoon, W.
A full understanding of the causes and effects of degradation of lithium-ion batteries for automotive applications therefore requires synergistic investigation across these length and time scales and with the combination of many experimental techniques.
UK-based Lithium-sulfur battery company OXIS Energy ( earlier post ) reported developing a Lithium-sulfur cell achieving in excess of 300 Wh/kg. OXIS CEO Huw Hampson-Jones says that the company is on schedule to release commercial cells for use in applications in the USA and Europe in 2015.
One of the major issues hobbling the commercialization of high energy-density lithium-sulfur batteries is the “polysulfide shuttle”—the shuttling of polysulfide ions between the cathode and anode. Top: Schematic of the electrochemical processes in a generic lithium-sulfur battery. C = Charge, D = Discharge.
A team at the University of Manchester (UK) has developed a doped graphene cathode for highly stable lithium-sulfur batteries. This technique is a one-step fabrication process without a binder to form a current collector for lithiumsulfur battery cathodes. C, 1 C, 2 C and 3 C charge rates. —Huang et al.
Lithium/sulfur cells are seen as a promising next-generation “beyond Li-ion” technology. 1 as well as very low cost, high abundance, and low environmental impact, sulfur is a promising cathode candidate. As a result, several research groups have been exploring the use of lithium sulfide (Li 2 S)—i.e., Batteries'
Researchers at Changchun University of Science and Technology in China have developed a nanobox strategy to improve the performance of lithium-sulfur batteries. 1 —five times than the commercialLithium-ion batteries—and practical energy densities of beyond 500 Wh kg ? 2018.10.032.
Phase 1 will be to lease around 20,000 sq meters to enable the production of 5 million Lithium-sulfur (Li-S) cells per year with the option to extend and double the estate and cell capacity. Reflecting its collaborative success with universities in the UK and Europe, OXIS is actively seeking collaborations with Brazilian universities.
Researchers at Tsinghua University have combined two types of carbon materials to create a new composite sulfur cathode material for a high-energy and high-power lithium-sulfur battery. 2014) “ Hierarchical Nanostructured Carbon/Sulfur Hybrid Cathode for High-Performance Lithium-Sulfur Battery ,” IMLB 17.
(b) Capacity retention of sulfur–TiO 2 yolk–shell nanostructures cycled at 0.5 C, in comparison with bare sulfur and sulfur–TiO 2 core–shell nanoparticles. The authors say that, to the best of their knowledge, this is the first time that a lithium–sulfur battery with this level of performance has been described.
The galvanostatic discharge and charge profiles of the first cycle of CMK-3 + sulfur; CMK-3/S-145; and CMK-3/S-155. While lithium-sulfur batteries use the flow of lithium ions in an electrolyte between an anode and a cathode, the way Li-S batteries store the ions is quite different. Source: Ji et al. Earlier post.).
The projects are based in 24 states, with approximately 47% of the projects led by universities; 29% by small businesses; 15% by large businesses; 7.5% University. Researchers from Colorado State University will develop a system. Researchers from Colorado State University will develop a system. University.
Under the European Union’s Horizon 2020 research and innovation program, the EU has launched ALISE (Advanced LithiumSulfur battery for xEV), a pan-European collaboration focused on the development and commercial scale-up of new materials and on the understanding of the electrochemical processes involved in lithium-sulfur technology.
Researchers at the University of Texas have discovered that introducing tellurium (Te) into a Li-Sulfur system as a cathode additive significantly improves the reversibility of Li plating/stripping by forming a tellurized and sulfide-rich solid-electrolyte interphase (SEI) layer on the Li surface. —Nanda et al. Nanda et al.
Purdue engineers have used upcycled low-density polyethylene (LDPE) plastic to boost the lifespan of lithium-sulfur batteries. When a PSC layer was utilized as an interlayer in lithium–sulfur batteries, the sulfur cathode delivered an improved capacity of 776 mAh g –1 at 0.5C Kim, Harif D. 8b03959.
Vorbeck, a manufacturer and developer of applications using its proprietary graphene material ( earlier post ), optioned the technology for use in a graphene-based electrode for lithium-air and lithium-sulfur batteries. Each year, pests cause many millions of dollars in damage to homes and commercial buildings.
Researchers at the University of Maryland have designed a flexible lithium-ion conducting ceramic textile featuring fast lithium-ion conductors, good electrochemical stability, and scalable processing approaches to device integration for solid-state lithium metal batteries. Gong et al. Click to enlarge. Earlier post.).
The projects, which are expected to run over four years, address battery challenges faced by industry and leverage the UK’s research capabilities to advance scientific knowledge with the aim of commercializing new battery technologies and processes. The project’s Principal Investigator is Professor Patrick Grant of the University of Oxford.
Researchers at The University of Texas at Dallas have used two-dimensional (2D) MoS 2 (molybdenum disulfide) as a protective layer for Li-metal anodes, greatly improving the performances of Li–S batteries. However, sulfur is a poor electrical conductor and can become unstable over just several charge-and-recharge cycles.
Founded in 2010 as a spin-off from Cornell University ( earlier post ), NOHMs Technologies currently has developed a battery that is based on lithium-sulfur chemistry, using its proprietary electrodes, ionic liquid based electrolyte and hybrid ceramic-polymer separator. LCO, NCA, LMNO, NMC and others).
PATHION is working on a derivative for Li-sulfur batteries as well as a derivative that could be applied in a sodium-ion battery. Lithiumsulfur. The first PATHION presentation described the role of LiRAP in a solid-state lithium-sulfur electrolyte.
A team of researchers in South Korea and Italy has demonstrated a highly reliable lithium–sulfur battery showing cycle performance comparable to that of commercially available lithium-ion batteries while offering more than double the energy density. Another major concern regarding the lithium?sulfur metal anode.
A team from the China University of Geosciences has taken a novel approach to stabilizing Lithium-sulfur batteries by functionalizing the carbon-sulfur cathode with DNA. Rechargeable lithium/sulfur battery promises an appealing candidate for energy storage to power portable devices and electric vehicles.
Researchers led by Dr. Yi Cui at Stanford University have demonstrated a new proof-of-concept lithium metal-free battery with high specific energy consisting of a lithium sulfide (Li 2 S)/mesoporous carbon composite cathode and a silicon (Si) nanowire anode. Credit: ACS, Yang et al. Click to enlarge. Yang et al.
Vorbeck Materials , a startup company based in Jessup, Maryland, is using a Pacific Northwest National Laboratory (PNNL)-developed method for developing graphene for better lithium air and lithiumsulfur batteries. The US Department of Energy (DOE) is now kicking off a second year of “America’s Next Top Energy Innovator.”.
Established in 2012 as a spin-out company from the University of Colorado Boulder, Solid Power is focused on developing and scaling competitive solid-state batteries, paying special attention to safety, performance, and cost. Earlier post.). The battery developer recently moved into a state-of-the-art facility in Louisville, Colorado.
Researchers at Drexel University have stabilized a rare monoclinic ?-sulfur sulfur phase within carbon nanofibers that enables successful operation of Lithium-Sulfur (Li-S) batteries in carbonate electrolyte for 4000 cycles. AN open-access paper on their work is published in Communications Chemistry. —Pai et al.
BioSolar’s cathode technology, which has been the primary focus of its university-led research and development efforts, is a novel conductive polymer material that leverages fast redox-reaction properties rather than conventional lithium-ion intercalation chemistry to enable rapid charge and discharge. Earlier post.).
One of the main obstacles to the commercialization of high-energy density lithium-sulfur batteries is the tendency for lithium polysulfides—the lithium and sulfur reaction products—to dissolve in the battery’s electrolyte and travel to the opposite electrode permanently. 1 after the 50 th cycle.
Researchers from University of Western Ontario, Lawrence Berkeley National Laboratory (LBNL), and Canadian Light Sources (CLS) have developed a safe and durable high-temperature Li-sulfur battery using universal conventional carbon–sulfur (C-S) electrodes with a molecular layer deposited (MLD) alucone (aluminum oxide polymeric film) coating.
Researchers at the Hong Kong University of Science and Technology have developed a high-capacity, long-life lithium-sulfur battery using a bi-functional cathode substrate for Li–S batteries made of well-distributed boron carbide nanoparticles decorated activated cotton fiber (B 4 C-ACF).
Cycling performance of the different samples (the specific capacity was calculated by using the active material mass (sulfur) of the composites, given in mA h g -1 ). Li-S batteries face a number of commercialization challenges, including electrolyte-soluble polysulfides. Demir-Cakan et al. Click to enlarge.
New composite materials based on selenium (Se) sulfides used as the cathode in a rechargeable lithium-ion battery could increase Li-ion density five times, according to research carried out at the US Department of Energy’s Advanced Photon Source at Argonne National Laboratory. Recently, lithium?sulfur sulfur (Li/S) and lithium?oxygen
Light-weighting materials : Five projects awarded to accelerate commercial availability of lighter weight vehicles using advanced materials that dramatically reduce vehicle weight while maintaining the highest safety standards. The Pennsylvania State University. The Regents of the University of California, Riverside.
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