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Electrochemical performance of the modified hollow carbon nanofiber cathode. (a) a) Specific capacities of the PVP modified sulfur cathode at C/5, C/2 and 1C cycling rates. (b) Lithiumsulfur batteries are of great interest due to their high specific energy and relatively low cost (e.g., Credit: ACS, Zheng et al.
Researchers from Hanyang University in Korea and the University of Rome Sapienza (Italy) have developed a lithium-sulfur battery employing a high-performance mesoporous hard carbon spherules-sulfur cathode and a stable, highly conducting electrolyte. 2012), An Advanced Lithium-Sulfur Battery.
Kentucky Governor Steve Beshear announced that start-up lithium-sulfur battery company NOHMs (Nano Organic Hybrid Materials) Technologies Inc. has selected to locate its research, manufacturing and product development facility for military, cell phone and electric vehicle lithium-ion batteries in Lexington.
The relationship between cathode porosity and predicted cathode-specific volumetric energy density e v (a) and gravimetric energy density e g (b) of the hybrid Mo 6 S 8 /S 8 cathode with all carbon included (HMSC) and C/S 8 cathode with different C/S 8 and Mo 6 S 8 /S 8 ratios. The net effect of using the new material is substantial.
Researchers at the Helmholtz-Zentrum Berlin für Materialien und Energie (HZB), with colleagues from Humboldt-Universität zu Berlin and University of Potsdam, have fabricated a nanomaterial made from nanoparticles of a titanium oxide compound (Ti 4 O 7 ) for use as a cathode material in lithium-sulfur batteries. Credit: HZB.
Researchers at Rice University led by Dr. James Tour have developed a hierarchical nanocomposite material of graphene nanoribbons combined with polyaniline and sulfur (Sulfur-PANI-GNRs, SPG) using an inexpensive, simple method.
Researchers at Toyohashi University of Technology in Japan have developed an active sulfur material and carbon nanofiber (S-CNF) composite material for all-solid-state Li-sulfur batteries using a low-cost and straightforward liquid phase process. Copyright Toyohashi University Of Technology. mA cm –2 ).
A team from Lawrence Berkeley National Laboratory and Tsinghua University (China) have synthesized graphene oxide-sulfur (GO-S) nanocomposite cathodes and applied them in lithium/sulfur cells to show a high reversible capacity of 950-1400 mAh g -1 and stable cycling for more than 50 deep cycles at 0.1C (1C = 1675 mA g -1 ).
Lithium-sulfur (Li-S) batteries, despite their high theoretical specific energy, face practical challenges including polysulfide shuttling and low cell-level energy density. The surface-mediated polysulfide redox behavior results in a much higher exchange current in comparison with MgO and carbon. 2018.09.024.
Researchers from Western University, Canadian Light Source, and the Chinese Academy of Sciences have proposed a novel solid-phase Li-S transformation mechanism that enables high energy Li-S batteries in conventional Li-ion carbonate electrolytes. Schematic of a lithiumsulfur battery in carbonate-based electrolyte.
Researchers at Tsinghua University have combined two types of carbon materials to create a new composite sulfur cathode material for a high-energy and high-power lithium-sulfur battery. Carbon atoms have six electrons: two are in 1s states, and four are valence electrons, occupying the 2s and 2p orbitals.
Researchers at Drexel University have stabilized a rare monoclinic ?-sulfur sulfur phase within carbon nanofibers that enables successful operation of Lithium-Sulfur (Li-S) batteries in carbonate electrolyte for 4000 cycles. sulfur and its application in Li-S batteries. —Pai et al.
Researchers at Jiangsu Normal University in China have devised a boron-doped carbon-sulfur (BCS) aerogel with consecutive “core-shell” stuctures as a binder-free cathode for lithium-sulfur batteries. Good porous structures of BCS aerogel can provide sufficient space for the expansion of active sulfur.
Vasant Kumar at the University of Cambridge and Professor Renjie Chen at the Beijing Institute of Technology has devised a three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C ZIF8-D ) composite to address performance-related issues in Lithium-sulfur batteries such as low efficiency and capacity degradation.
Researchers at Shanghai Jiao Tong University have developed a gel-like electrolyte induced by fumed alumina for dendrite-free Li deposition, lower over-potential and better cycle stability in lithium-sulfur batteries. An open-access paper on their work is published in the RSC journal Chemical Communications. —Lei et al.
ARPA-E’s first solicitation awarded $151 million to 37 projects aimed at transformational innovations in energy storage, biofuels, carbon capture, renewable power, building efficiency, vehicles, and other areas. Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Biodiesel. Earlier post.) Engineering E. per gallon.
A team of Researchers at Stanford University and SLAC National Accelerator Laboratory, led by Stanford’s Dr. Yi Cui, has developed a simple and scalable approach to utilizing Li 2 S (lithium sulfide) as the cathode material for rechargeable lithium-ion batteries with high specific energy. Credit: ACS, Yang et al.
Australia-based Li-S Energy has entered into an agreement with Janus Electric to develop and to test lithiumsulfur and/or lithium-metal battery cells to suit the requirements of the Janus Electric exchangeable prime mover battery packs. MWh) by the end of 2023, with additional demand growth expected in future years.
ARPA-E’s new program, Robust Affordable Next Generation Energy Storage Systems (RANGE) ( earlier post ), aims to accelerate widespread EV adoption by dramatically improving driving range and reliability, and by providing low-cost, low-carbon alternatives to today’s vehicles. University of Houston. Princeton University.
Researchers at South China Normal University in Guangzhou have developed a novel composite of sulfur loaded in micropore-rich carbon aerogel (CA-S) for use as a cathode in Li-sulfur batteries. These issues limit the practical application of lithium-sulfur battery. —Li et al. Click to enlarge.
The University of Michigan (U-M) and Shanghai Jiao Tong University (SJTU) have selected six research teams to share $1.05 The renewable energy projects are: Safe, high-performance lithium-sulfur batteries for electric vehicle applications. and Chinese governments, as well as from industry.
Researchers from The University of Queensland (Australia) have devised a composite cathode material for lithium-sulfur batteries: graphene-wrapped carbon nanospheres with sulfur uniformly distributed in between, in which the carbon nanospheres act as the sulfur carriers. 1 at a current rate of 0.1?C
Lithium-sulfur batteries are prospects for future batteries as they are made from cheaper and more environmentally friendly materials than lithium-ion batteries. A comprehensive description of electrochemical processes in the positive electrode of lithium-sulfur batteries is crucial for the utilization of active material.
When no carbon black was added to the electrode mixture, a very high Li 2 S content (88 wt % Li 2 S) electrode composed of 98 wt % 1 ? Lithium/sulfur cells are seen as a promising next-generation “beyond Li-ion” technology. carbon composites; trapping of polysulfides; and electrolyte modification. Click to enlarge.
The projects are based in 24 states, with approximately 47% of the projects led by universities; 29% by small businesses; 15% by large businesses; 7.5% University. Researchers from Colorado State University will develop a system. Researchers from Colorado State University will develop a system. University.
Researchers at Beihang University in Beijing have developed a linear molecule sulfur-rich organic material as sulfur cathode for a lithium-sulfur battery. The tetramethylthiuram disulfide-sulfur (TMTD-S) cathode material delivers an initial capacity of 685?mAh 1 at 0.2C (1?C?=?1061?mAh 1 after 200 cycles.
The galvanostatic discharge and charge profiles of the first cycle of CMK-3 + sulfur; CMK-3/S-145; and CMK-3/S-155. While lithium-sulfur batteries use the flow of lithium ions in an electrolyte between an anode and a cathode, the way Li-S batteries store the ions is quite different. Source: Ji et al. Earlier post.).
Schematic showing the chemical reduction reaction of one Li 2 S 6 molecule by lithium to form six Li 2 S molecules, involving the diffusion/driving of lithium out of the graphene layers in the graphite. S chemistry batteries and potentially could become applicable in lithium metal-free Li?air, Lithium-sulfur (Li?S)
Researchers from Central South University in Changsha, China, have developed a separator with a nitrogen-doped porous hollow carbon sphere (NHC) coating for use in Li-S batteries. The NHC-decorated separator enormously improves the utilization of active material and enhances electrochemical performance. 2015.09.067.
Purdue engineers have used upcycled low-density polyethylene (LDPE) plastic to boost the lifespan of lithium-sulfur batteries. They first prepared porous sulfonated carbon (PSC) from LDPE plastic via microwave-promoted sulfonation. with cycle retention of 79% over 200 cycles. —Kim et al.
Schematic of design and fabrication process of hollow carbon nanofibers/sulfur composite structure. To tackle the polysulfide problem, researchers at Stanford University led by Dr. Yi Cui have developed a hollow carbon nanofiber-encapsulated sulfur cathode for effective trapping of polysulfides. Click to enlarge.
Researchers at Changchun University of Science and Technology in China have developed a nanobox strategy to improve the performance of lithium-sulfur batteries. 1 —five times than the commercial Lithium-ion batteries—and practical energy densities of beyond 500 Wh kg ? 2018.10.032.
Researchers from Hanyang University in Korea and the University of Maryland have developed a sulfur-carbon nanotube (S/SWNT) composite coated with polyaniline (PANI) polymer as polysulfide block to achieve high sulfur utilization, high Coulombic efficiency, and long cycle life in Li-Sulfur batteries.
A team at Cornell University has used ice-templating to synthesize hierarchical porous carbons (HPCs) with extremely high surface areas of up to 2340 m 2 g −1 with total pore volume of up to 3.8 cm 3 g −1 as supports for sulfur for electrodes in Li–S batteries. Ritu Sahore, Luis P. Estevez, Anirudh Ramanujapuram, Francis J.
Stanford University scientists have created a new ultrahigh surface area three-dimensional porous graphitic carbon material that significantly boosts the performance of energy-storage technologies. The maximum surface area achieved with conventional activated carbon is about 3,000 m 2 g –1.
Researchers at The University of Texas at Dallas have used two-dimensional (2D) MoS 2 (molybdenum disulfide) as a protective layer for Li-metal anodes, greatly improving the performances of Li–S batteries. However, sulfur is a poor electrical conductor and can become unstable over just several charge-and-recharge cycles.
Researchers at Tsinghua University (China) report in a paper in ChemSusChem on their use of both lithium anode passivation and polysulfide anion diffusion suppression strategies to reduce self-discharge of the lithium–sulfur cell. —Xu et al. Huang, J. -J., and Zhang, Q. 201500428.
(b) Capacity retention of sulfur–TiO 2 yolk–shell nanostructures cycled at 0.5 C, in comparison with bare sulfur and sulfur–TiO 2 core–shell nanoparticles. The authors say that, to the best of their knowledge, this is the first time that a lithium–sulfur battery with this level of performance has been described.
The US Department of Energy (DOE) is awarding $60 million to 24 research and development projects aimed at reducing carbon dioxide emissions from passenger cars and light- and heavy-duty trucks. (DE-FOA-0002420) SUNY University @ Stony Brook. AOI 1b: Liquid Electrolytes for Lithium-Sulfur (Li-S) Cells. . Giner, Inc.
The new battery combines a Li 2 S/mesoporous carbon composite cathode and a silicon nanowire anode. The lithium/sulfur system, which during the redox process behaves according to the reaction 2Li + S ? CMK-3 carbon is made up of hexagonally arranged 7-8 nm thick carbon nanorods separated by 3-4 nm pores.
Schematic of the synthesis steps for a graphene-sulfur composite material, with a proposed schematic structure of the composite. Researchers at Stanford University led by Drs. However, it remains challenging to retain high and stable capacity of sulfur cathodes over more than 100 cycles.In Credit: ACS, Wang et al.
Researchers from Hunan University and Changsha University in China have designed 3D hierarchical porous nitrogen-doped aligned carbon nanotubes (HPNACNTs) with well-directed 1D conductive electron paths as scaffold to load sulfur for use as a high-performance cathode in Li-S batteries. —Deng et al. 2016.05.024.
optioned a PNNL-developed method for building titanium oxide and carbon structures that greatly improve the performance of lithium-ion batteries. The new material stores twice as much electricity at high charge/discharge rates as current lithium ion batteries, and creates increased battery capacity and a longer cycle life.
Researchers at Cornell University are proposing a new scheme for cathodes for lithium-sulfide batteries ( earlier post ) to prevent lithium polysulfide dissolution and shuttling during electrochemical cycling. polyacrylonitrile), to control the distribution of lithium sulfide in the host material. Credit: ACS, Guo et al.
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