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MIT researchers propose mechanism for overcoming bottleneck in electroreduction of CO2

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This article proposes a model that accounts for the modes in which aqueous gas depletion evolves over time and affects the long-term CO 2 electroreduction and the corresponding pH evolution near the electrode’s surface. Therefore, the extent to which H 2 is produced can be used as a metric to evaluate the efficiency of CO 2 RR.

MIT 284
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China team develops efficient multifunctional catalyst for conversion of CO2 to gasoline-range hydrocarbons

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During CO 2 hydrogenation, CO 2 is initially reduced to CO by hydrogen via the reverse water-gas shift (RWGS) on Fe 3 O 4 sites, followed by a subsequent hydrogenation of CO to α-olefins via Fischer–Tropsch synthesis (FTS) on Fe 5 C 2 sites.

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Zinc Orthogermanate Nanoribbons Support Improved Photocatalytic Reduction of CO2 to Renewable Methane

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Researchers at Nanjing University and Anhui Polytechnic University in China have synthesized zinc orthogermanate (Zn 2 GeO 4 ) ultralong nanoribbons which show promising photocatalytic activity toward the reduction of CO 2 into renewable methane (CH 4 ) and water. Article ASAP doi: 10.1021/ja1068596. —Liu et al.

Renewable 186
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Rice researchers find amines cross-linked with buckyballs an effective, selective CO2 absorbent

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The lab produced a brown, spongy material in which hydrophobic (water-avoiding) buckyballs forced the hydrophilic (water-seeking) amines to the outside, where passing carbon dioxide could bind to the exposed nitrogen. The Rice lab used buckyballs as crosslinkers between amines, nitrogen-based molecules drawn from polyethyleneimine.

CO2 199
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New highly selective and efficient catalyst for reduction of CO2 to CO

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Testing under identical conditions confirmed the non-porous silver catalyst’s significant advantages over other silver catalysts in water environments. Chen & Feng Jiao (2014) “A selective and efficient electrocatalyst for carbon dioxide reduction,” Nature Communications 5, Article number: 3242 doi: 10.1038/ncomms4242.

CO2 210
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Researchers Propose a Renewable Energy Cycle Based on Co-electrolysis of Water and CO2 to Produce Syngas

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The direct fuel cell produces electricity, with water and CO 2 as byproducts of the oxidation of the liquid fuel in the fuel cell. Although there are “ open issues ” with longevity, the SOEC devices have “ good performance ” in splitting water, the authors note. Energy Fuels , Article ASAP doi: 10.1021/ef900111f.

Water 150
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Researchers show mixotrophic fermentation process improves carbon conversion, boosting yields and reducing CO2

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To avoid CO 2 emissions associated with H2-production, electrolysis of water powered by solar, wind or hydroelectricity would be a preferred source and has achieved a level of maturity and success. Alternatively, syngas can be added to sugar fermentation to provide the necessary reducing power and carbon. … Antoniewicz, Eleftherios T.