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MIT: hybrid cathodes could boost energy capacity of lithium-sulfur batteries

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Researchers at MIT and in China are proposing a new class of dense intercalation-conversion hybrid cathodes by combining intercalation-type Mo 6 S 8 with conversion-type sulfur (HMSC) to realize a Li–S full cell. Typical sulfur cathodes are made up of 20 to 30 percent carbon, he says, but the new version needs only 10 percent carbon.

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China team devises boron-doped carbon-sulfur aerogel with consecutive core-shell structures for high-capacity, long-life Li-S battery

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Researchers at Jiangsu Normal University in China have devised a boron-doped carbon-sulfur (BCS) aerogel with consecutive “core-shell” stuctures as a binder-free cathode for lithium-sulfur batteries. Good porous structures of BCS aerogel can provide sufficient space for the expansion of active sulfur.

Carbon 220
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Sulfur-loaded carbon aerogel as cathode for Li-S battery offers improved cyclic stability

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Researchers at South China Normal University in Guangzhou have developed a novel composite of sulfur loaded in micropore-rich carbon aerogel (CA-S) for use as a cathode in Li-sulfur batteries. These issues limit the practical application of lithium-sulfur battery. —Li et al. Click to enlarge.

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Graphene oxide-sulfur (GO-S) nanocomposite cathodes for high-capacity, stable cycling lithium sulfur batteries

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A team from Lawrence Berkeley National Laboratory and Tsinghua University (China) have synthesized graphene oxide-sulfur (GO-S) nanocomposite cathodes and applied them in lithium/sulfur cells to show a high reversible capacity of 950-1400 mAh g -1 and stable cycling for more than 50 deep cycles at 0.1C (1C = 1675 mA g -1 ).

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Nitrogen-doped porous hollow carbon sphere-decorated separators enhance performance of Li-S batteries

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Researchers from Central South University in Changsha, China, have developed a separator with a nitrogen-doped porous hollow carbon sphere (NHC) coating for use in Li-S batteries. The NHC-decorated separator enormously improves the utilization of active material and enhances electrochemical performance. 2015.09.067.

Carbon 150
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Graphene sheet-sulfur/carbon composite cathode for higher performance Li-sulfur batteries

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Vasant Kumar at the University of Cambridge and Professor Renjie Chen at the Beijing Institute of Technology has devised a three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C ZIF8-D ) composite to address performance-related issues in Lithium-sulfur batteries such as low efficiency and capacity degradation.

Carbon 218
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Tsinghua team explores strategies to reduce Li-S battery self-discharge

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Researchers at Tsinghua University (China) report in a paper in ChemSusChem on their use of both lithium anode passivation and polysulfide anion diffusion suppression strategies to reduce self-discharge of the lithiumsulfur cell. —Xu et al. Huang, J. -J., and Zhang, Q. 201500428.