Chinese researchers develop self-powered system for recycling of LFP batteries via triboelectric nanogenerator
07 August 2023
A research team in China has developed an innovative self-powered system comprising an electrochemical Li-ion battery (LIB) recycling reactor and a triboelectric nanogenerator (TENG) for recycling spent LFP batteries. A paper on their work appears in the RSC journal Energy & Environmental Science.
In the electrochemical LIB recycling reactor, the Cl−/ClO− pair generated electrochemically in NaCl solution is adopted as the redox mediator to break down LFP into FePO4 and Li+ via a redox targeting reaction without extra chemicals.
Additionally, a TENG that utilizes discarded components from LIBs including casings, aluminum-plastic films and current collectors is designed to drastically minimize secondary pollutants. The TENG harvests wind energy, delivering an output of 0.21 W for powering the electrochemical recycling system and charging batteries.
The proposed system for recycling spent LFP exhibits high purity (Li2CO3, 99.70% and FePO4, 99.75%), self-powered features, simplified treatment procedure and a high profit, which can promote the sustainability of LIB technologies, the researchers said.
Zhang et al.
Lithium iron phosphate batteries (LFPs) represent more than 32% of the worldwide lithium-ion battery (LIB) market share. State-of-the-art recycling technologies, which are typically based on electrochemical or chemical leaching methods, have critical issues such as tedious procedures, enormous chemical/electricity consumption and secondary pollution.
Resources
Baofeng Zhang, Lixia He, Jing Wang, Yuebo Liu, Xu Xue, Shengnan He, Chuguo Zhang, Zhihao Zhao, Linglin Zhou, Jie Wang and Zhong Lin Wang (2023) “Self-powered recycling of spent lithium iron phosphate batteries via triboelectric nanogenerator” Energy Environ. Sci. doi: 10.1039/D3EE01156A
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