Researchers in Europe led by a team from ETH Zurich have designed a fuel production system that uses water, CO₂, and sunlight to produce aviation fuel. The team implemented the system at pilot-scale in the field to demonstrate the technical feasibility of the entire sun-to-liquid fuel process chain, from H₂O and CO₂ to kerosene. An open-access paper on the work is published in the journal Joule.

We are the first to demonstrate the entire thermochemical process chain from water and CO₂ to kerosene in a fully-integrated solar tower system.

—Aldo Steinfeld, a professor from ETH Zurich and the corresponding author of the paper

Previous attempts to produce aviation fuels through the use of solar energy have mostly been performed in the laboratory.

The aviation sector is responsible for about 5% of global anthropogenic emissions causing climate change. It relies heavily on kerosene (jet fuel)—a liquid hydrocarbon fuel typically derived from crude oil.

(A) Schematic of the solar tower fuel plant, encompassing the solar tower concentrating facility, the solar reactor, and the GtL unit. A heliostat field concentrates the direct normal solar irradiation onto a solar reactor mounted on top of the solar tower. The solar reactor co-splits H₂O and CO₂ and produces a specific mixture of H2 and CO (syngas), which in turn is processed to liquid hydrocarbon fuels using the FT-based GtL unit located next to the solar tower base. All sub-systems are operated from the control room.
(B) Photograph of the solar tower fuel plant during operation. Zoller et al.

With our solar technology, we have shown that we can produce synthetic kerosene from water and CO₂ instead of deriving it from fossil fuels. The amount of CO₂ emitted during kerosene combustion in a jet engine equals that consumed during its production in the solar plant. That makes the fuel carbon neutral, especially if we use CO₂ captured directly from the air as an ingredient, hopefully in the not-too-distant future.

—Aldo Steinfeld

The solar-made kerosene is fully compatible with the existing aviation infrastructure for fuel storage, distribution, and end use in jet engines, Steinfeld says. It can also be blended with fossil-derived kerosene.

Schematic of the solar reactor for splitting H₂O and CO₂ via the ceria-based thermochemical redox cycle. It consists of a cavity-receiver containing a ceria RPC structure directly exposed to concentrated solar radiation entering through a windowed circular aperture. During the reduction step, the RPC is exposed to the high solar fluxes; O₂ evolves. During the oxidation step, reacting gases CO₂ and H₂O enter via tangential inlet ports at the front and flow across the porous RPC; syngas is formed. Product gases (O₂ during the reduction step, syngas during the oxidation step) exit via an axial port at the rear of the vessel. Zoller et al.

In 2017, the team started scaling up the design and built a solar fuel-production plant at IMDEA Energy Institute in Spain. The plant consists of 169 sun-tracking reflective panels that redirect and concentrate solar radiation into a solar reactor mounted on top of a tower.

The concentrated solar energy then drives oxidation-reduction (redox) reaction cycles in the solar reactor, which contains a porous structure made of ceria. The ceria—which is not consumed but can be used repeatedly—converts water and CO₂ injected into the reactor into syngas, a tailored mixture of hydrogen and carbon monoxide. Subsequently, syngas is sent into a gas-to-liquid converter, where it is finally processed into liquid hydrocarbon fuels that include kerosene and diesel.

During a nine-day run of the plant reported in the paper, the solar reactor’s energy efficiency—the portion of solar energy input that is converted into the energy content of the syngas produced—was around 4%. Steinfeld says his team is working intensively on improving the design to increase the efficiency to values over 15%.

For example, they are exploring ways to optimize the ceria structure for absorbing solar radiation and developing methods to recover the heat released during the redox cycles.

This work is supported by Swiss State Secretariat for Education, Research and Innovation, and the EU Horizon 2020 research and innovation program.

Resources

• Zoller et al. (2022) “A solar tower fuel plant for the thermochemical production of kerosene from H₂O and CO₂” Joule doi: 10.1016/j.joule.2022.06.012