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$12M German project to develop technology for syngas production from CO2 and H2; new hydrogen production method

BASF, the Linde Group and ThyssenKrupp plan to develop an environmentally friendly and competitive basis for utilizing carbon dioxide as a raw material on an industrial scale. Together with BASF’s subsidiary hte AG and scientific partners VDEh-Betriebsforschungsinstitut, Düsseldorf, and TU Dortmund University, the companies are developing a two-stage process.

In the first step, an novel high-temperature technology will process natural gas to obtain hydrogen and carbon. Compared to other processes, this technology produces much less CO2.

In a subsequent catalytic process step, the hydrogen is then reacted with large volumes of CO2, also from other industrial processes, to produce syngas. A mixture of carbon monoxide and hydrogen, syngas is a key raw material for the chemical industry and is also suitable for producing fuels.

The German Federal Ministry of Education and Research (BMBF) is granting a total of €9.2 million (US$12 million) to subsidize the project within its “Technologies for Sustainability and Climate Protection – Chemical Processes and Use of CO2” scheme. The project started on 1 July 2013, and is expected to last three years.

Together with our project partners, we aim to develop a technology that will open up innovative ways of producing the basic key chemicals hydrogen and syngas on an industrial scale from natural gas, a resource that will be available for the long term. In hydrogen production alone, we expect CO2 emissions to be about 50% lower than in current standard processes. At the same time, this process produces hydrogen at particularly competitive costs.

—Dr. Peter Schuhmacher, President, BASF SE Process Research & Chemical Engineering

The natural gas decomposition is achieved thermally only, without any addition of oxygen or water. This enables the production of hydrogen and solid carbon; the latter may potentially be used to replace hard coal in the coke and steel industries.

With the process operating at very high temperatures, the innovative reactor design ensures that the correspondingly large amounts of waste heat are recycled immediately into the process.

BASF is coordinating the joint project and, in cooperation with hte, carrying out the experimental research activities on gas decomposition and the catalyst development for the production of syngas. Based on this, the partners intend to develop a pilot plant design and a concept for integrating the innovative technology into existing chemical and steel-producing sites. The engineering responsibility lies with Linde and ThyssenKrupp Uhde. ThyssenKrupp Steel Europe and its subsidiary Kokereibetriebsgesellschaft Schwelgern (KBS) will perform the carbon conditioning and testing for steel industry use.

Comments

Davemart

This is potentially very important.

The steel industry is one of the biggest energy users in the world, and the very high grade coal they use is getting scarcer and more expensive.

This means that an important resource can be created as a by product of producing transport fuel.

Very much win-win.

Alain

This technology could eventually also be an efficient method for carbon sequestration. If (bonedry) biomass is used instead of NG, a lot of H2 can be produced from it, together with solid carbon for easy sequestration. As long as coal is used as a carbon source, this biochar should of course replace coal. Once no solid carbon is needed anymore, this is a possible method for massive carbon sequestration in solid form. The solid carbon is probably a good fertilizer.

Engineer-Poet

The flip side of this is that a suitable anode electrode was recently discovered for the electrolytic production of elemental iron, so smelting's days may be over.

Darius

Why somebody wants waist energy and produce hydrogen instead of using directly gas,NG or electricity. Better design dragsters or F1 bolids. That would be at least nice looking at.

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